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Demolition Means Progress? An Interview With Author Andrew Highsmith – Belt Magazine

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Efficient deep blue-violet fluorophores are highly sought after as emitters for OLEDs and as labels for fluorescent imaging. Here we describe the preparation of two violet-blue emitters based on hexamethylazatriangulene HMAT donors and weakly accepting sulfone and sulfoxide acceptors, with CIE coordinates in solution as low as 0. By restricting freedom of motion in the HMAT donor, stability of the sp 2 C—N bonds is increased significantly, increasing photostability over controls with nonplanar donors while also narrowing the emission bandwidth to
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